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With the recent developments in strong-state electrolyte, the conductivity from the strong-state electrolyte at room temperature can be equivalent or maybe more substantial than that from the liquid electrolyte. However, only couple scientific tests have already been completed to analyze the Li dendrite advancement within reliable electrolyte and liquid crystalline electrolyte. The nucleation and dendrite development mechanism for strong and liquid crystalline electrolytes needs to be further examined. Determined by the experimental scientific studies about aqueous hybrid electrolyte battery in recent years, it has been found that hybrid ions can inhibit the dendrite growth107,108.
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Experiments and calculations confirmed which the diffusion of Li in FePO4 crystal has strong anisotropic and LixFePO4 contains a strong inclination to separate the sound phase of Li-prosperous and Li-poor14,15,16. However, in 2011, Bai et al.17 challenged the idea. Their perform demonstrated that stage separation is dynamically inhibited when the battery is operating at much larger current, since the reaction limitation in nanoparticles do away with the thermodynamic driving power. Bazant and colleagues18 even more investigated the coherent non-equilibrium subsurface period morphologies in LixFePO4 nanoparticles in 2018 and the final results showed which the anisotropy on the interface plays a significant purpose in determining the morphology with the subsurface stage. Recently, Fleck et al.19 produced a continuum section-industry design taking into consideration anisotropic (orthorhombic) and inhomogeneous elastic results to simulate the diffusion-limited phase transformation for the duration of Li intercalation in LiFePO4 nanoparticles.
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